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ENGINEERING
THERMODYNAMICS

by

Dr. S. S. Khandare

This book on Engineering Thermodynamic contains basic principles and fundamental laws of Thermal Engineering. It deals with the gas laws and properties of fluids like pressure, temperature and volume.

The book discusses the thermodynamic processes like isothermal, isentropic and polytropic processes. The new concept of availability and irreversibility has been included in the book.

The various properties like enthalpy, entropy, internal energy of steam are discussed. The topics on properties of steam and steam cycles like rankine, modified rankine cycles are also presented in the book.

The various air standard cycles are analysed and numerical problems are presented throughout the book. The key topics in the book are:

* Gas laws and properties
* Thermodynamic process
* Availability of air standard cycles
* Properties of steam and steam cycles
* Flow processes
* Fuels and combustion
* Short questions for viva voce
* Steam tables with mollier diagram — enthalpy-entropy charts, etc.
The book contains:
* 141
* 426
* 219
* 115
*   40
Solved numerical examples
Exercises for practice
Objective questions
Self-explanatory and neatly drawn sketches
Useful tables
.
The book is intended to serve as an introductory text-book for the students of Engineering reading for Degree Examinations of almost all the Universities of India, Diploma Examinations conducted by various Boards of Technical Education, Certificate courses, as well as for the U.P.S.C. and A.M.I.E. Examinations.
Price : Rs. 150-00 $ 10-00 £ 7-50
Edition : First Edition : 2003
ISBN : 81-85594-21-X
Book Size : 170 mm × 240 mm
Binding : Paperback with Four Colour Jacket Cover
Pages : 320 + 16 (With mollier diagram)
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CONTENTS

Chapter 1 : INTRODUCTION

Chapter 2 : GAS LAWS AND PROPERTIES

Chapter 3 : THERMODYNAMIC PROCESSES

Chapter 4 : AVAILABILITY

Chapter 5 : AIR STANDARD CYCLES

Chapter 6 : PROPERTIES OF STEAM AND STEAM CYCLE

Chapter 7 : FLOW PROCESSES

Chapter 8 : FUELS AND COMBUSTION

APPENDICIES
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DETAILED CONTENTS

Chapter 1 : INTRODUCTION

1-1
1-2
1-3
1-4
1-5
Heat engines
Engineering thermodynamics
Working fluids and thermodynamic system
Thermodynamic state and thermodynamic process
System of units
(i)
(ii)
SI system
Metric system

1-6
1-7
1-8
1-9
1-10
1-11
1-12
1-12-1

1-12-2
1-13
1-14
1-15
1-15-1
1-15-2
1-15-3
1-15-4
1-16

1-17
1-18
1-19
1-20

1-21

Units of length, area and volume
Specific volume
Units of mass
Units of force
Units of work and power
Units of energy
Measurements of properties of fluid
Pressure
Exercises 1-1
Temperature
Zeroth law of thermodynamics
Temperature measurement
Pyrometers
Thermo-electric pyrometer
Radiation pyrometer
Optical pyrometer
Pyrometric cone or seger cone pyrometer
Absolute temperature scale and absolute zero
Exercises 1-2
NTP and STP conditions
Volume
Work
Heat
Exercises 1-3
Properties of substances
Objective questions
Exercises 1-4

Chapter 2 : GAS LAWS AND PROPERTIES

2-1
2-2
2-3

2-4

2-5
2-6
2-7
2-8
2-9

2-10
2-11
2-12
2-13
2-14
2-15
2-16
2
-17

2-18
2-18-1
2-18-2

2-19
2-20
2-21
2-22
2-23

Perfect gas
Vapour
Boyle’s law
Exercises 2-1
Charles’ law
Exercises 2-2
Combination of laws of Boyle and Charles
Vander Waal's equation
Units of R
Universal gas constant
Avogadro’s law
Exercises 2-3
Accountability of energy
Joule’s law of internal energy
Enthalpy
Entropy
Intensive and extensive properties
Thermodynamic system
Conservation of energy
First law of thermodynamics
Exercises 2-4
Concepts of the second law of thermodynamics
Kelvin-Plank statement
Clausius statement
Exercises 2-5
Specific heats of a gas
Ratio of specific heats
Relation between the two specific heats of a gas and the specific gas constant
General equation for entropy changes for ideal gases
Properties of gas mixtures
Objective questions
Answers to objective questions
Exercises 2-6

Chapter 3 : THERMODYNAMIC PROCESSES

3-1
3-2
3-3
3-4
3-5

3-6

3-7

3-8
3-9
3-10
3-11
3-12

3-13
3-13-1
3-13-2
3-13-3
3-14
3-15

3-16

Expansion and compression of gases
Point and path functions
Process
Constant volume process
Constant pressure process
Exercises 3-1
Isothermal process
Exercises 3-2
Isentropic process
Exercises 3-3
Polytropic process
Determination of the index of expansion or compression
Comparison of work done by a gas during expansion for various processes
Mean effective pressure
Summary of equations for gas processes
Exercises 3-4
Other important processes
Hyperbolic expansion
Free expansion
Throttling
Gas tables
Approximation for heat absorbed
Exercises 3-5
Typical examples
Objective questions
Answers to objective questions
Exercises 3-6

Chapter 4 : AVAILABILITY

4-1
4-2
Reversibility
Available energy and availability
(i)
(ii)
Heat withdrawn from an infinite reservoir
Heat withdrawn from a finite reservoir

4-2-1
4-2-2
4-2-3
4-3
4-4
4-5

Decrease in available energy
Availability of a finite system
Availability in a closed system
Effectiveness
Irreversibility
Available energy and physical concept of entropy
Exercises 4-1

Chapter 5 : AIR STANDARD CYCLES

5-1
5-2
5-3
5-4
5-5
5-6
5-7
5-8

5-9
5-10

5-11
5-12

5-13

5-14

5-15

5-16
5-17
5-18

Introduction
Heat machine
Useful work
Efficiency of cycle
Air standard efficiency of cycle
Assumptions in the thermodynamic cycles
Thermodynamic cycles
Carnot cycle
Exercises 5-1
Otto cycle
Mean effective pressure
Exercises 5-2
Diesel cycle
Dual combustion cycle
Exercises 5-3
Stirling cycle
Exercises 5-4
Ericsson cycle
Exercises 5-5
Brayton cycle
Exercises 5-6
Comparison of ideal cycles
Reversed Brayton cycle (Bell Coleman cycle)
Coefficient of performance (COP)
Objective questions
Answers to objective questions
Exercises 5-7

Chapter 6 : PROPERTIES OF STEAM AND STEAM CYCLE

6-1
6-2
6-3
6-4
6-5
6-6
Properties of steam
Conservation of form
Phase diagram
Effect of pressure on the boiling point of water
Temperature-pressure curve for steam
Generation of one kg of steam at a given pressure from water initially at 0°C
(1)
(2)
(3)
Introducing stage
Warming stage
Evaporating stage


6-7

6-8
6-9
6-10
6-11
6-12
6-13
6-14
6-15
6-16
6-17
6-18
6-19
6-20

6-21

Exercises 6-1
Conditions of steam
Saturated steam
Dry saturated steam and wet steam
Superheated steam
Supersaturated steam
Properties of steam
Dryness fraction of saturated steam
Use of steam tables
Sensible heat
Latent heat of vaporization
Enthalpy of wet steam
Enthalpy of superheated steam
Specific volume of steam
Internal energy of steam
Exercises 6-2
Entropy of vapours
(1)
(2)
(3)
Entropy of water
Entropy of evaporation
Entropy of superheated steam

6-22

6-23
6-24
6-25
Exercises 6-3
Temperature–entropy diagram
Heat entropy chart (mollier chart)
Pressure-enthalpy chart
Heating and expansion of vapours
(1)
(2)
(3) (4)
(5)
(6)
(7)
Constant volume process
Constant pressure process
Constant temperature (Isothermal) process
Hyperbolic (PV = constant) process
Polytropic process
Reversible adiabatic or Isentropic process
Throttling process

6-26
6-27

6-28

6-29

6-30

6-31
6-32
6-33
6-34
6-35
6-36

Methods of determination of dryness fraction of steam
Bucket calorimeter
Exercises 6-4
Separating calorimeter
Exercise 6-5
Throttling calorimeter
Exercises 6-6
Combined separating and throttling calorimeter
Exercises 6-7
Steam cycle
Carnot cycle
Rankine cycle
Comparison of Rankine and Carnot cycles on temperature-entropy diagram
Work done during Rankine cycle on pressure-volume diagram
Modified Rankine cycle
Objective questions
Answers to objective questions
Exercises 6-8

Chapter 7 : FLOW PROCESSES

7-1
7-2
Flow Processes
Steady flow energy equation
(1)
(2)
(3) (4)
(5)
(6)
Internal energy
Kinetic energy
Potential energy
Flow work
Work
Heat

7-3
7-4
7-5

Control volume and flow work
Flow work of steady flow system
Applications of steady-flow energy equation
(1)
(2)
(3) (4)
(5)
(6)
(7)
(8)
(9) (10)
Steam turbines
Boilers
Heat exchangers
Nozzles
Throttle valves
Reciprocating compressor
Gas turbine
Water turbine
Centrifugal compressor
Centrifugal water pump
Objective questions
Answers to objective questions
Exercises 7-1

Chapter 8 : FUELS AND COMBUSTION

8-1
8-2
8-3
8-4
8-5
8-6
8-7

8-8
8-9
8-10

8-11
8-12
8-13

8-14
8-14-1
8-14-2
8-14-3
8-14-4
8-15
8-16

8-17

8-18
8-19
8-20

Classification of fuels
Solid fuels
Liquid fuels
Hydrocarbons
Gaseous fuels
Calorific value of fuels
Theoretical determination of calorific value of fuel
Exercise 8-1
Calorific value of gaseous fuels
Experimental determination of calorific value of a fuel
Bomb calorimeter
Exercises 8-2
Calorific value of liquid fuels
Calorific value of gaseous fuels
Junker’s gas calorimeter
Exercises 8-3
Combustion of a fuel
Combustion of carbon
Combustion of carbon monoxide
Combustion of hydrogen
Combustion of sulphur
Stoichiometric air–fuel ratio
Excess air
Exercises 8-4
Determination of the flue gas analysis by mass and by volume
Exercises 8-5
Determination of air supplied from volumetric analysis of flue gases
Determination of air leakage in boiler flues
Determination of the quantity of air supplied per kg of fuel from the analysis of flue gases when given by mass
Exercises 8-6

8-21
8-21-1
8-21-2
8-21-3
8-21-4

8-22

8-23

Chemically correct air fuel ratio
Combustion of hydrogen
Combustion of carbon monoxide
Combustion of marsh gas
Excess air coefficient
Exercises 8-7
Determination of flue gas analysis by volume and by mass in case of gaseous fuel
Exercises 8-8
Determination of quantity of air supplied per m3 of gas from dry flue gas analysis in case of gaseous fuels
Exercises 8-9
8-24
8-25
8-25-1
8-25-2
Calculation of heat losses
Exhaust gas analysis
Conventional method
Modern methods
(1)
(2)
(3) (4)
Gas chromatography
Non-destructive infra red analyzer
Flame ionization detector
Measurement of smoke

8-26

Determination of air-fuel ratio with the help of dry flue gas analysis
Objective questions
Answers to objective questions
Exercises 8-10

APPENDICIES

APPENDIX A
APPENDIX B 
Short Questions for Viva-voce
Steam Table
Table B-I  : PROPERTIES OF SATURATED STEAM AND
                    SATURATED WATER (TEMPERATURE BASE)
Table B-II :
PROPERTIES OF SATURATED STEAM AND
                     SATURATED WATER (PRESSURE BASE)